They taste quite different. Mezcal has a very smokey taste...VERY smokey. That is due to the way it is made. The agave pinas are roasted in earthen ovens, or usually fire pits, whereas tequila is steamed cooked. The roasting gives Mezcal the smokey taste. I have heard some people say it is similar to an Islay Single Malt Scotch.
So far I have tried Del Maguey Chichicapa, and just last weekend tried Ilegal reposado. They are both quite good, but the Ilegal is simply amazing. Of course both are pretty expensive as well. Maybe someone can recommend a bargain brand, but in my experience even a decent Mezcal is over $50USD, usually over $70.
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