Don Valente is the route to go, it is not available in North Carolina and I can specificly direct you to retailers that carry DV!
It really depends on where you stop though. Spec's in Austin has the best tequila selection by far IMHO (I havent searched too hard), the Warehouse is near the airport, off I-35. A google map search will find it for you...I would say they have at least 150 tequila brands.
I have no idea about the tequila selection in North Carolina. But it is northern east coast and tequila is not quite as popular in some areas up there. Go through the reviews and check out some brands you may be interested in, shoot me a PM and I can let you know if I've seen them in Texas. I am located about 1 1/2 hours north of Austin.
I must emphasize Don Valente, it is AMAZING and worth every penny. The brand is solid all the way through (blanco, repo, anejo). You will not be disapointed.
another to keep your eye on...El Gran Jubileo is supposed to be great and if your going for a long shot...TequilaME, the extra anejo is now available around here and I have not tried it yet. There are LOTS of brands available in Texas. It seems Cali, Texas, Colorado, Florida, and Arizona are the hot spots for tequila.
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Tequila Don Valente....ask for it.
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